平成30年度発足 新学術領域研究
発動分子科学

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研究成果 - B01

【原著論文】      【書籍/総説・解説】

原著論文
A turn-on mode fluorescent diarylethene having an azacrown ether receptor: Metal-ion-gated enhancement of the photoreactivity and fluorescence
S. Takaku, R. Nishimura, *M. Morimoto, Dyes and Pigments,216, 111354 (2023), DOI: 10.1016/j.dyepig.2023.111354

Efficient surface peeling, a photoinduced result of photochromic diarylethene crystal by multistep light irradiation
*Y. Nakagawa, M. Morimoto, S. Yokojima, S. Nakamura, *K. Uchida, Cryst. Growth Des.,23,1581-1591 (2023), DOI: 10.1021/acs.cgd.2c01202

Diarylethene isomerization by using triplet-triplet annihilation photon upconversion
R. Nishimura, Y. Nagakawa, *M. Morimoto, Chem. Eur. J.,29,e202203651 (2023), DOI: 10.1002/chem.202203651

Multicolor Photochromism of Two-Component Diarylethene Crystals Containing Oxidized and Unoxidized Benzothiophene Groups
*W. Larsson, M. Morimoto, M. Irie, *J. Andréasson, *B. Albinsson, Crystals,12,1730 (2022), DOI: 10.3390/cryst12121730

Anion-Dominated Redox of a SAM of an Alkylthiolated Viologen Bearing a Covalently-attached Intramolecular Sulfonate Group on a Gold Electrode
M. Toyohara, *T. Sagara, Electrochemistry,90, 117004 (2022), DOI: 10.5796/electrochemistry.22-00099

Durable Gelfoams Stabilized by Compressible Nanocomposite Microgels
Y. Nishizawa, T.Watanabe, T. Noguchi, M. Takizawa, C. Song, K. Murata, H. Minato, *D. Suzuki, Chem. Commun.,58, 12927-12930 (2022), DOI: 10.1039/D2CC04993G

Phototunable golden luster microcrystalline film of photochromic diarylethene
*Y. Nakagawa, R. Nishimura, M. Morimoto, S. Yokojima, S. Nakamura, *K. Uchida, Bull. Chem. Soc. Jpn.,95, 1438-1444 (2022), DOI: 10.1246/bcsj.20220169

Adsorption Races of Binary Colloids with Different Softness at the Air/water Interface of Sessile Droplets
H. Minato, Y. Sasaki, K. Honda, T. Watanabe, *D. Suzuki, Adv. Mater. Interfaces,9, 2200879 (2022), DOI: 10.1002/admi.202200879

White light emission generated by two stacking patterns of a single organic molecular crystal
*Y. Nakagawa, K. Kinoshita, M. Kasuno, R. Nishimura, M. Morimoto, S. Yokojima, M. Hatakeyama, Y. Sakamoto, S. Nakamura, *K. Uchida, Mater. Adv.,3, 6466-6473 (2022), DOI: 10.1039/D2MA00670G

Comparison between polycrystalline Au and single-crystalline Au (111) electrodes as the substrate of a cationic organic monolayer based on their anion dependent redox activities
*T. Sagara, M. Toyohara, J. Electroanal. Chem.,919,116514 (2022), DOI: 10.1016/j.jelechem.2022.116514

Photoinduced cytotoxicity of photochromic symmetric diarylethene derivatives: the relation of structure and cytotoxicity
Y. Nakagawa, T. Hishida, E. Hatano, *K. Sumaru, K. Morishita, M. Morimoto, S. Yokojima, S. Nakamura, *K. Uchida, Org. Biomol. Chem.,20,3211-3217 (2022), DOI: 10.1039/D2OB00224H

Turn-on mode fluorescent diarylethene having neopentyl substituents that undergoes all-visible-light switching
R. Nishimura, E. Fujisawa, I. Ban, R. Iwai, S. Takasu, *M. Morimoto, *M. Irie, Chem. Commun.,58, 4715-4718 (2022), DOI: 10.1039/D2CC00554A

Controlling the shell structure of hard core/ hydrogel shell microspheres
Y. Nishizawa, K. Honda, M. Karg, *D. Suzuki,Colloid and Polymer Science,300,333-340 (2022), DOI:10.1007/s00396-021-04934-2

Visualization of the microstructure and the position-dependent diffusion coefficient in a blended polymer solid using photo-activation localization microscopy combined with single-molecule tracking based on one-color fluorescence-switching of diarylethene
*S. Ito, M. Funaoka, I. Hanasaki, S. Takei, M. Morimoto, M. Irie, *H. Miyasaka, Polym. Chem.,13, 736-740 (2022), DOI: 10.1039/D1PY01100F

Sheet-Like Supramolecular Assembly of Amphiphilic Diarylethene Showing Photoinduced Transformation Formed by Depletion Force
H. Yasuda, *K. Higashiguchi, *K. Matsuda,Chem. Lett.,50,1875-1878 (2021), DOI: 10.1246/cl.210452

Molecular crystalline capsules that release their contents by light
A. Nagai, R. Nishimura, Y. Hattori, E. Hatano, A. Fujimoto, M. Morimoto, N. Yasuda, K. Kamada, H. Sotome, H. Miyasaka, S. Yokojima, S. Nakamura, *K. Uchida, Chem. Sci.,12, 11585-11592 (2021), DOI: 10.1039/D1SC03394H

Photochemically switchable interconnected microcavities for all-organic optical logic gate
Hendra, A. Takeuchi, H. Yamagishi, O. Oki, M. Morimoto, M. Irie, *Y. Yamamoto,Adv. Funct. Mater.,31, 2103685 (2021), DOI: 10.1002/adfm.202103685

High-frequency Swelling/Deswelling Oscillation of Poly (Oligoethylene Glycol) Methacrylate Based Hydrogel Microspheres with a Tris (2,2′-bipyridyl) ruthenium Catalyst
K. Inui, I. Saito, R. Yoshida, H. Minato, *D. Suzuki,ACS Applied Polymer Materials,3,3298–3306 (2021), DOI:10.1021/acsapm.1c00153

Recent Development in the Visualization of Microgels
Y. Nishizawa, K. Honda, *D. Suzuki, Chem. Lett.,50,1226-1235 (2021), DOI:10.1246/cl.210028

Redox of Viologen for Powering and Coloring
*T. Sagara, H. Tahara, Chem. Rec.,21, 2375-2388 (2021),DOI: 10.1002/tcr.202100082

Photoinduced topographical surface changes and photoresponse of the crystals of 7-methoxycoumarin
K. Yano, R. Nishimura, Y. Hattori, M. Morimoto, H. Sugiyama, T. Kamitanaka, S. Yokojima, S. Nakamura, *K. Uchida,CrystEngComm,23, 5780-5787 (2021), DOI: 10.1039/D1CE00444A

Re-entrant Photoinduced Morphological Transformation and Temperature‐Dependent Kinetic Products of a Rectangular‐Shaped Amphiphilic Diarylethene Assembly
Y. Kotani, H. Yasuda, *K. Higashiguchi, *K. Matsuda,Chem. Eur. J.,27,11158-11166 (2021), DOI: 10.1002/chem.202101127

Non-close-packed arrangement of soft elastomer microspheres on solid substrate
Y. Sasaki, S. Hiroshige, M. Takizawa, Y. Nishizawa, T. Uchihashi, H. Minato, *D. Suzuki, RSC Advances,11, 14562-14567 (2021), DOI:10.1039/D1RA02688G

Nanostructure and thermoresponsiveness of poly (N-isopropyl methacrylamide)-based hydrogel microspheres prepared via aqueous free radical precipitation polymerization
Y. Nishizawa, H. Minato, T. Inui, I. Saito, T. Kureha, M. Shibayama, *T. Uchihashi, *D. Suzuki, RSC Advances,11, 13130 (2021), DOI:10.1039/D1RA01650D

Fluorescence Switchable Conjugated Polymer Microdisk Arrays by Cosolvent Vapor Annealing
H. Yamagishi, T. Matsui, Y. Kitayama, Y. Aikyo, L. Tong, J. Kuwabara, T. Kanbara, M. Morimoto, M. Irie, *Y. Yamamoto, Polymers,13, 269 (2021), DOI: 10.3390/polym13020269

Stepwise assembly of ultrathin poly (vinyl alcohol) films on photoresponsive diarylethene crystals
H. Chiba, M. Morimoto, Chem. Lett.,50, 84-86 (2021), DOI: 10.1246/cl.200693

Enhancement of deformation of redox-active hydrogel as an actuator by increasing pendant viologens and adding filler or counter-charged polymer
B. Wang, H. Tahara, *T. Sagara, Sens. Actuators B Chem.,331,129359 (2021), DOI: 10.1016/j.snb.2020.129359

Nanostructures, Thermoresponsiveness, and Assembly Mechanism of Hydrogel Microspheres during Aqueous Free-Radical Precipitation Polymerization
Y. Nishizawa, H. Minato, T. Inui, *T. Uchihashi, *D. Suzuki, Langmuir,37, 151–159 (2021), DOI: DOI:10.1021/acs.langmuir.0c02654

In Situ Surface-enhanced Raman Scattering Spectroscopic Study of a Redox-active Deformable Hydrogel on a Roughened Au Electrode Surface
B. Wang, B. G. daFonseca, A. G. Brolo, *T. Sagara, Chem. Lett.,50, 467-470 (2021), DOI: 10.1246/cl.200766

Effect of an Underlying Monolayer of a Nafion Film upon Redox Reaction of Methyl Viologen on a Au Electrode
T. Ayabe, *T. Sagara, Electrochemistry,89, 131-133 (2021), DOI: 10.5796/electrochemistry.20-00132

Photoinduced swing of a diarylethene thin broad sword shaped crystal: a study on the detailed mechanism
A. Fujimoto, N. Fujinaga, R. Nishimura, E. Hatano, L. Kono, A. Nagai, A. Sekine, Y. Hattori, Y. Kojima, N. Yasuda, M. Morimoto, S. Yokojima, S. Nakamura, B. L. Feringa, *K. Uchida, Chem. Sci.,11,12307-12315 (2020), DOI: 10.1039/D0SC05388K

A cytosolically localized far-red to near-infrared rhodamine-based fluorescent probe for calcium ions
K. Numasawa, *K. Hanaoka, T. Ikeno, H. Echizen, T. Ishikawa, M. Morimoto, T. Komatsu, T. Ueno, Y. Ikegaya, T. Nagano, *Y. Urano,Analyst,145,7736-7740 (2020), DOI: 10.1039/D0AN01739F

Gas-Dependent Reversible Structural and Magnetic Transformation between Two Ladder Compounds
J. Manabe, K. Nishida, X. Zhang, Y. Nakano, M. Fujibayashi, G. Cosquer, K. Inoue, S. Shimono, H. Ishibashi, Y. Kubota, M. Shiga, R. Tsunashima, Y. Tatewaki, *S. Nishihara, CRYSTALS,10,841 (2021), DOI:10.3390/cryst10090841

Synthesis and Solid-State Polymerization of 5-(Pyren-1-yl)penta-2,4-diyn-1-ol Derivatives with an N-Phenylurethane or N-Benzylurethane Group
S. Oshimizu, S. Takeshi, T. Sato, R. Yamakado, Y. Tatewaki, S. Okada, Cryst. Growth Des,20,6356-6365 (2020), DOI: 10.1021/acs.cgd.0c00438

Electrowetting of Hydrofluoroether Liquid Droplet at a Gold Electrode/Water Interface: Significance of Lower Adhesion Energy and Static Friction Energy
T. Morooka, *T. Sagara,Langmuir,36,9685-9692 (2020), DOI: 10.1021/acs.langmuir.0c00829

Electrochemical and spectroelectrochemical probing of the ionic channel in Nafion films using the redox of perfluoroalkyl viologen
T. Ayabe, A. Chen,*T. Sagara,J. Electroanal. Chem.,873,114442: 1-12 (2020), DOI: 10.1016/j.jelechem.2020.114442

STM apparent height measurements of molecular wires with different physical length attached on 2-D phase separated templates for evaluation of single molecular conductance
T. Iizuka, D. Shimizu, *K. Matsuda,RSC Adv.,10,22054-22057 (2020), DOI: 10.1039/D0RA04484A

Thermoresponsive structural changes of single poly(N-isopropyl acrylamide) hydrogel microspheres under densely packed conditions on a solid substrate
H. Minato, Y. Nishizawa, *T. Uchihashi, *D. Suzuki, Polym.J. ,52,1137–1141 (2020), DOI:10.1038/s41428-020-0372-3

Cyclization from higher excited states of diarylethenes having a substituted azulene ring
*Y. Hattori, T. Maejima, Y. Sawae, J. Kitai, M. Morimoto, R. Toyoda, H. Nishihara, S. Yokojima, S. Nakamura, K. Uchida, Chem. Eur. J. , 26,11441-11450 (2020), DOI:10.1002/chem.202001671

Turn-on mode fluorescent diarylethenes:
Effect of electron-donating and electron-withdrawing substituents on photoswitching performance

R. Iwai, *M. Morimoto, M. Irie, Photochem. Photobiol. Sci.,19,783-789 (2020), DOI: 10.1039/D0PP00064G

Optical microresonator arrays of fluorescence-switchable diarylethenes with unreplicable spectral fingerprints
D. Okada, Z. H. Lin, J. S. Huang, O. Oki, M. Morimoto, X. Liu, T. Minari, S. Ishii, T. Nagao, M. Irie, *Y. Yamamoto, Mater. Horiz., 71801-1808 (2020), DOI: 10.1039/D0MH00566E

The Belousov-Zhabotinsky Reaction in Thermoresponsive Core-Shell Hydrogel Microspheres with a Tris(2,2’-bipyridyl) ruthenium Catalyst in the Core
T. Watanabe, Y. Nishizawa, H. Minato, S. Chihong, *K. Murata, and *D. Suzuki, Angew. Chem. Int. Ed., 59, 8849-8853(2020), DOI: 10.1002/anie.202003493

Hydrophobic monomers recognize microenvironments in hydrogel microspheres during free radical
seeded emulsion polymerization

T. Watanabe, Y. Nishizawa, H. Minato, S. Chihong, *K. Murata, and *D. Suzuki, Angew. Chem. Int. Ed., 59, 8849-8853(2020), DOI: 10.1002/anie.202003493

A diarylethene annulated isomer as a highly-conductive molecular wire evaluated by the exchange interaction between two nitroxides
Y. Sumiya, K. Higashiguchi, *K. Matsuda, Chem. Commun., 56, 2447-2450 (2020), DOI: 10.1039/C9CC10017B

One-dimensional molecular nano-branched structures of tetrathiafulvalene derivative with crown ether
S. Nakamura, T. Takei, S. Nishihara, S. Okada, T. Akutagawa, T. Nakamura and *Y. Tatewaki, Jpn. J. Appl. Phys., 59, SDDA10 (2019), DOI: 10.7567/1347-4065/ab5914

Fluorination effect on electrochemistry of dibutyl viologen in aqueous solution
S. Nakamura, T. Ayabe, B. Chan, *T. Sagara, J. Electroanal. Chem., 856, 113691 (2020), DOI: 10.1016/j.jelechem.2019.113691

Inorganic–Organic Hybrid Photomechanical Crystals Consisting of Diarylethenes and Cage Siloxanes
R. Kajiya, S. Sakakibara, H. Ikawa, *K. Higashiguchi, K. Matsuda, H. Wada, K. Kuroda, *A. Shimojima, Chem. Mater., 31, 9372-9378 (2019), DOI: 10.1021/acs.chemmater.9b02941

Photoinduced repetitive separation of a supramolecular assembly composed of an amphiphilic
diarylethene mixture

S. Sakakibara, H. Yotsuji, *K. Higashiguchi, *K. Matsuda, Soft Matter, 15, 7918-7925 (2019), DOI: 10.1039/C9SM01301F

An all-photonic full color RGB system based on molecular photoswitches
G. Naren, C. W. Hsu, S. Li, M. Morimoto, S. Tang, J. Hernando, G. Guirado, M. Irie, F. M. Raymo, H. Sunden, *J. Andreasson, Nature Commun., 10, 3996 (2019), DOI: 10.1038/s41467-019-11885-4

Protein uptake into individual hydrogel microspheres visualized by high-speed atomic force microscopy
S. Matsui, K. Hosho, H. Minato, *T. Uchihashi, *D. Suzuki
Chem. Commun., 55, 10064-10067(2019), DOI: 10.1039/c9cc05116c

Object transportation system mimicking the cilia of Paramecium aurelia making use of the
light-controllable crystal bending behavior of a photochromic diarylethene

*R. Nishimura, A. Fujimoto, N. Yasuda, M. Morimoto, T. Nagasaka, H. Sotome, S. Ito, H. Miyasaka, S. Yokojima, S. Nakamura, B. L. Feringa, *K. Uchida, Angew. Chem. Int. Ed., 58, 13308-13312 (2019), DOI: 10.1002/anie.201907574

Effect of Charge Groups Immobilized in Hydrogel Microspheres during the Evaporation of
Aqueous Sessile Droplets

H. Minato, M. Takizawa, S. Hiroshige, *D. Suzuki, Langmuir, 35, 10412-10423(2019),
DOI: 10.1021/acs.langmuir.9b01933

Thermally reversible photochromism of dipyrrolylethenes
K. Inaba, R. Iwai, M. Morimoto, *M. Irie, Photochem. Photobiol. Sci., 18, 2136-2141 (2019), DOI: 10.1039/C8PP00557E

The polymorphism of porphyrin 2D assemblies at the liquid–graphite interface:
the effect of a polar solvent additive and a flexible spacer on the face-on and edge-on
type molecular arrangements

K. Adachi, *T. Hirose, *K. Matsuda, Chem. Commun., 55, 8836-8839 (2019),
DOI: 10.1039/C9CC02579K

Non‐Thermoresponsive Decanano‐sized Domains in Thermoresponsive Hydrogel Microspheres Revealed by Temperature‐Controlled High‐Speed Atomic Force Microscopy
Y. Nishizawa, S. Matsui, K. Urayama, T. Kureha, M. Shibayama, *T. Uchihashi and *D. Suzuki, Angew. Chem. Int. Ed.,58, 8809-8813 (2019), DOI:10.1002/anie.201903483

Hydrogel Microellipsoids that Form Robust String‐Like Assemblies at the Air/Water Interface
K. Honda, Y. Sazuka, K. Iizuka, S. Matsui, T. Uchihashi, T. Kureha, M. Shibayama, T. Watanabe, *D. Suzuki, Angew. Chem. Int. Ed., 58, 7294-7298 (2019), DOI:10.1002/anie.201901611

書籍/総説・解説
・「Photosynergetic responses in molecules and molecular aggregates」,H. Miyasaka, K. Matsuda, J. Abe, T. Kawai, “Photoinduced Morphological Transformation and Photodriven Movement of Objects Using Self-Assembly of Amphiphilic Diarylethene in Water”, K. Higashiguchi, *K. Matsuda, Springer, 327-348 (2020), ISBN: 978-981-15-5450-6

・ケミカルエンジニアリング,
“電子欠損性ホウ素化合物を利用した物質変換反応”,
庄子良晃・*菓子田 惇輝・*福島孝典, 有機合成化学協会誌, 78, 190-203 (2020), DOI: 10.5059/yukigoseikyokaishi.78.190

・「コロイド結晶の形成とその応用」,中村浩,山中淳平, “第4章 いろいろなコロイド結晶 第3節 ハイドロゲル微粒子からなるコロイド結晶”, 本田健士郎, 湊遥香, 佐々木悠馬, 鈴木大介*, シーエムシー出版, 150-158 (2020), ISBN: 978-4-7813-1502-7

・「Photosynergetic responses in molecules and molecular aggregates」,H. Miyasaka, K. Matsuda, J. Abe, T. Kawai, “Turn-on mode photoswitchable fluorescent diarylethenes for super-resolution fluorescence microscopy”, *M. Morimoto, M. Irie, Springer, 563-580 (2020), ISBN: 978-981-15-5450-6

・「基礎高分子科学 第2版(高分子学会 編)」, 高原 (Ed) , “ナノゲル” , 鈴木大介, 東京化学同人, (2020), 372, ISBN: 978-4-8079-0962-9

・「ナノファイバーの製造・加工技術と応用事例」, “水素結合を導入した導電性分子からなるゲルの作製と分子性ナノファイバ-の電気物性評価” , *帯刀陽子, 技術情報協会, 388-392 (2019), ISBN: 978-4-86104-765-7

・「光機能性有機・高分子材料における新たな息吹」, 市村國宏 (Ed) , “光スイッチ機能をもつ蛍光分子の設計と合成” , 森本正和, 入江正浩, シーエムシー出版, 239-250 (2019), ISBN: 978-4-7813-1414-3

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