平成30年度発足 新学術領域研究
発動分子科学

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研究成果 - A01-1

【原著論文】      【書籍/総説・解説】

原著論文
Dipole-moment-induced supramolecular assembly of a donor–acceptor-type molecule on a metal surface and in a crystal
*W. Nakanishi, Y. Matsushita, M. Takeuchi, *K. Sagisaka, Phys. Chem. Chem. Phys., 25, 13702-13707 (2023), DOI: 10.1039/D2CP05982G

Dense and Acidic Organelle-Targeted Visualization in Living Cells: Application of Viscosity-Responsive Fluorescence Utilizing Restricted Access to Minimum Energy Conical Intersection
J. Adachi, H. Oda, T. Fukushima, B. Lestari, H. Kimura, H. Sugai, K. Shiraki, R. Hamaguchi, K. Sato, *K. Kinbara Anal. Chem., 955196–5204 (2023), DOI: 10.1021/acs.analchem.2c04133

Sensitivity Tuning of 9,10-Di(piperazinyl)anthracene Derivatives for Amphiphilic Assemblies by pH and Side-chain Modification with Monodisperse Oligo (Ethylene Glycol)s
J. Adachi, *K. Kinbara Chem. Lett., 52,218–221 (2023), DOI: 10.1246/cl.230025

Extended tripodal hydrotris (indazol-1-yl) borate ligands as ruthenium-supported cogwheels for on-surface gearing motions
*K. Omoto, M. Shi, K. Yasuhara, C. Kammerer, *G. Rapenne Chem. Eur.J., 29, e202203483 (2023), DOI: 10.1002/chem.202203483

Thermally responsive morphological changes of layered coordination polymers induced by disordering/ordering of flexible alkyl chains
*K. Omoto, S. Aoyama, T. Galica, E. Nishibori, S. Katao, K. Yasuhara, *G. Rapenne Dalton Trans., 51,17967-17972 (2022), DOI: 10.1039/D2DT03142F

Multiblock Amphiphilic Triptycene toward Bioinspired Molecular Rotor in Membrane
*W. Yospanya, K. Sato, *K. Kinbara Chem. Lett., 51,1026–1028 (2022), DOI: 10.1246/cl.220360

Supramolecular Mechanosensitive Potassium Channel Formed by Fluorinated Amphiphilic Cyclophan
*K. Sato, R. Sasaki, R. Matsuda, M. Nakagawa, T. Ekimoto, T. Yamane, M. Ikeguchi, K. V. Tabata, H. Noji, *K. Kinbara J.Am.Chem.Soc., 144,11802–11809 (2022), DOI: 10.1021/jacs.2c04118

Thermal and redox properties of Donor-Acceptor foldamers consisting of tetrathiafulvalene and viologen
*T. Ikeda, W. Nakanishi, Mater. Today Chem., 24,100863 (2022), DOI: 10.1016/j.mtchem.2022.100863

Oxidation-degree-dependent moisture-induced actuation of a graphene oxide film
*W. Nakanishi, Y. Yamauchi, Y. Nishina, M. Yoshio, M. Takeuchi, RSC Advances, 123372-3379 (2022), DOI:10.1039/D1RA07773B

Nanocars based on Polyaromatic or Porphyrinic Chassis
T. Nishino, C. Martin, K. Yasuhara, *G. Rapenne, J. Synth. Org. Chem. Jpn., 79,1050-1055 (2021), DOI:10.5059/yukigoseikyokaishi.79.1050

Supramolecular Transmembrane Ion Channels Formed by Multiblock Amphiphiles
*K.Sato, T.Muraoka, *K. Kinbara, BMC Biology , 54, 3700-3709 (2021), DOI:10.1021/acs.accounts.1c00397

Photophysical properties of 1,2,3,4,5-pentaarylcyclopentadienyl hydrotris(indazolyl) borate ruthenium(II) complexes
S. Gao, Y. Gisbert, G. Erbland, S. Abid, C. Kammerer, A. Venturini, *G. Rapenne, *B. Ventura, N. Armaroli, Phys. Chem. Chem. Phys , 23, 17049-17056 (2021), DOI:10.1039/D1CP02261J

Divergent synthesis of molecular winch prototypes
Y. Gisbert,S. Abid, C. Kammerer, *G. Rapenne, Chem. Eur. J. , 27, 16242-16249 (2021), DOI:10.1002/chem.202103126

Energy storage upon photochromic 6-π photocyclization and efficient on-demand heat release with oxidation stimuli
*K.Sato, T.Muraoka, *K. Kinbara, J. Phys. Chem. Lett, 12, 11391-11398 (2021), DOI:10.1021/acs.jpclett.1c03052

Molecular gears: from solution to surfaces
Y. Gisbert, S. Abid, C. Kammerer, *G. Rapenne, Chem. Eur. J., 27, 12019-12031 (2021), DOI:10.1002/chem.202101489

Properties of Imidazolinium-containing Multiblock Amphiphile in Lipid Bilayer Membranes
M. Mori and *K. Kinbara, J. Photopolym. Sci. Technol., 34, 161–165 (2021), DOI: 10.2494/photopolymer.34.161

Ruthenium complexes of sterically-hindered pentaarylcyclopentadienyl ligands
R. Asato, C. Martin, Y. Gisbert, S. Abid, T. Kawai, C. Kammerer, *G. Rapenne, RSC Advances, 11, 20207-20215 (2021), DOI:10.1039/D1RA03875C

Characterization of a novel type of carbonic anhydrase that acts without metal cofactors
Y. Hirakawa, M. Senda, K. Fukuda, H. Y. Yu, M. Ishida, M. Taira, K. Kinbara & T. Senda, BMC Biol., 19, 105 (2021), DOI: 10.1186s12915-021-01039-8

Calcium-induced reversible assembly of phosphorylated amphiphile within lipid bilayer membranes
Y. Shimizu, K. Sato, *K. Kinbara, Chem. Commun., 57, 4106-4109 (2021), DOI: 10.1039/D1CC01111A

The Emergence of Multiple Coordination Numbers in Gold–Cyanoarene Complexes: A Study of the On-Surface Coordination Mechanism
*W. Nakanishi, *A. Nakata, P. Perez, M. Takeuchi, C.Joachim, and *K. Sagisaka, J. Phys. Chem. C., 125, 9937–9946 (2021), DOI: 10.1021/acs.jpcc.1c02456

Molecular rotor functionalized with a photoresponsive brake
R. Asato, C. J. Martin, S. Abid, Y. Gisbert, F. Asanoma, T. Nakashima, C. Kammerer, T. Kawai, *G. Rapenne, Inorg. Chem., 60, 3492-3501 (2021), DOI: 10.1021/acs.inorgchem.0c03330

Desymmetrised pentaporphyrinic gears mounted on metallo-organic anchors
M. Kojima, N. Saffon-Merceron, J. Cuny, *C. Kammerer, *G. Rapenne, Chem. Sci., 12, 4709-4721 (2021), DOI: 10.1039/d0sc06379g

Synthetic Ion Channel Formed by Multiblock Amphiphile with Anisotropic Dual-Stimuli-Responsiveness
R. Sasaki, K. Sato, Ka. V. Tabata, H. Noji, *K. Kinbara, J. Am. Chem. Soc., 143,1348–1355(2021), DOI: 10.1021/jacs.0c09470

Imidazolinium‐based Multiblock Amphiphile as Transmembrane Anion Transporter
M. Mori, K. Sato, T. Ekimoto, S. Okumura, M. Ikeguchi, K. V. Tabata, H. Noji, *K. Kinbara, Chem. Asian J., 16, 147-157 (2020), DOI: 10.1002/asia.202001106

Mechanics of molecule-gears with six long teeth
*W.H. Soe, M. Kleinwächter, C. Kammerer, G. Rapenne, C. Joachim, J. Phys. Chem. C, 124,22625-22630 (2020), DOI: 10.1021/acs.jpcc.0c08194

Helicity Manipulation of a Double-Paddled Binaphthyl in a Two-Dimensional Matrix Field at the Air–Water Interface
M. Ishii, *T. Mori, W. Nakanishi, J. P. Hill, H. Sakai, *K. Ariga, ACS Nano., 14, 13294-13303 (2020), DOI: 10.1021/acsnano.0c05093

Transmitting stepwise rotation among three molecule-gear on the Au (111) surface
T. Kühne, F. Eisenhut, M. Kleinwächter, Y. Gisbert, R. Robles, N. Lorente, G. Cuniberti, C. Joachim, G. Rapenne, C. Kammerer, *F. Moresco, J. Phys. Chem. Lett., 11, 6892-6899 (2020), DOI: 10.1021/acs.jpclett.0c01747

Thermo-driven self-assembly of a PEG-containing amphiphile in a bilayer membrane
R. Li, T. Muraoka, *K. Kinbara, RSC Adv., , 10, 25758-25762 (2020), DOI: 10.1039/D0RA03920A

Discrete π Stack of a Tweezer‐Shaped Naphthalenediimide–Anthracene Conjugate
S. K. Keshri, W. Nakanishi, A. Takai, T. Ishizuka, T. Kojima, *M. Takeuchi, Chem. Eur. J. , 26, 13288-13294 (2020) , DOI: 10.1002/chem.202002477

Dipolar nanocars based on a porphyrin backbone
T. Nishino, C. Martin, H. Takeuchi, F. Lim, K. Yasuhara, Y. Gisbert, S. Abid, N. Saffon-Merceron, C. Kammerer, *G. Rapenne, Chem. Eur. J. , 26, 12010-12018 (2020), DOI: 10.1002/chem.202001999

A synthetic ion channel with anisotropic ligand response
*T. Muraoka, D. Noguchi, R. S. Kasai, K. Sato, R. Sasaki, K. V. Tabata, T. Ekimoto, M. Ikeguchi, K. Kamagata, N. Hoshino, H. Noji, T. Akutagawa, K. Ichimura, *K. Kinbara, Nat. Commun. , 11, 2924 (2020), DOI:10.1038/s41467-020-16770-z

Reversible formation of multiple stimuli-responsive polymeric materials through processing control of trifunctional amphiphilic molecules
*T. Muraoka, H. Honda, K. Nabeya, *K. Kinbara, Chem. Commun. , 56, 7881-7884 (2020), DOI: 10.1039/D0CC02716B

Systematic studies of structural variations in terarylene photohydride generators
C. Martin, J. Patrick Calupitan, M. Minamide, R. Asato, Y. Goto, G. Rapenne, T. Nakashima, *T. Kawai, J. Photochem Photobiol. A , 397, 112594 (2020), DOI: 10.1016/j.jphotochem.2020.112594

Hydrogen Bonds and Molecular Orientations of Supramolecular Structure between Barbituric Acid and Melamine Derivative at the Air/Water Interface Revealed by Heterodyne-Detected Vibrational Sum Frequency Generation Spectroscopy.
M. Okuno, S. Yamada, T. *Ohto, H. Tada, W. Nakanishi, K. Ariga, *T. Ishibashi, J. Phys. Chem. Lett. , 11, 2422-2429 (2020), DOI: 10.1021/acs.jpclett.0c00329

Aromatic Fluorination of Multiblock Amphiphile Enhances Its Incorporation into Lipid Bilayer Membranes
R. Sasaki, *K. Sato, *K. Kinbara, Chemistryopen , 9, 301-303 (2020), DOI: 10.1002/open.201900374

New Modified Deoxythymine with Dibranched Tetraethylene Glycol Stabilizes G-Quadruplex Structures
H. Tateishi-Karimata, T. Ohyama, T. Muraoka, S. Tanaka, K. Kinbara, Molecules, , 25, 705 (2020), DOI: 10.3390/molecules25030705

The lipid composition affects Trastuzumab adsorption at monolayers at the air-water interface
A. Sakai, A. P. de Sousa Mesquista, H. B. Nader, C. C. Lopes, W. Nakanishi, K. Ariga, *L. Caseli, Chem. Phys. Lip. , 227, 104875 (2020), DOI: 10.1016/j.chemphyslip.2020.104875

Modular synthesis of pentaarylcyclopentadienyl Ru-based molecular machines via sequential Pd-catalysed cross couplings
Y. Gisbert, S. Abid, G. Bertrand, N. Saffon-Merceron, C. Kammerer, *G. Rapenne, Chem. Commun. , 55, 14689-14692 (2019), DOI: 10.1039/c9cc08384g

Star-shaped ruthenium complexes as prototypes of molecular gears
G. Erbland, S. Abid, Y. Gisbert, N. Saffon‐Merceron, Y. Hashimoto, L. Andreoni, T. Guérin, C. Kammerer, *G. Rapenne, Chem. Eur. J. , 25, 16328-16339 (2019), DOI: 10.1002/chem.201903615

A chiral molecular propeller designed for unidirectional rotations on a surface
Y. Zhang, J.P. Calupitan, T. Rojas, R. Tumbleson, G. Erbland, C. Kammerer, T.M. Ajayi, S. Wang,
L.C. Curtiss, A.T. Ngo, S.E. Ulloa, G. Rapenne, S.W. Hla, Nat. Commun. , 10, 3742 (2019), DOI: 10.1038/s41467-019-11737-1

Monitoring Fluorescence Response of Amphiphilic Flapping Molecules in Compressed Monolayers at the Air–Water Interface
*W. Nakanishi, *S. Saito, N. Sakamoto, A. Kashiwagi, S. Yamaguchi, H. Sakai, *K. Ariga Chem. Asian J., 14, 2869-2876 (2019), DOI: 10.1002/asia.201900769

Development of an Engineered Photoactive Yellow Protein as a Cross‐Linking Junction for Construction of Photoresponsive Protein‐Polymer Conjugates
M. Ui, Y. Miyauchi, M. Inoue, M. Murakami, Y. Araki, T. Wada, *K. Kinbara, ChemPhotoChem , 3, 356-360 (2019), DOI: 10.1002/cptc.201900024

Photochromic diarylethenes designed for surface deposition: from self-assembled monolayers to single molecules
J. P. D. C. Calupitan, O. Galangau, T. Nakashima, T. Kawai, *G. Rapenne, ChemPlusChem, 84, 564–577 (2019), DOI: 10.1002/cplu.201800640

Dynamic Control of Intramolecular Rotation by Tuning the Surrounding Two-Dimensional Matrix Field
*T. Mori, H. Chin, K. Kawashima, H. T. Ngo, N.-J. Cho, W. Nakanishi, J. P. Hill, *K. Ariga, ACS Nano., 13, 2410–2419 (2019), DOI: 10.1021/acsnano.8b09320

Heat-Triggered Crystallization of Liquid Crystalline Macrocycles Allowing for Conductance Switching through Hysteretic Thermal Phase Transitions
T. Muraoka, T. Shima, T. Kajitani, N. Hoshino, E. Morvan, A. Grélard, E. J. Dufourc, T. Fukushima, T. Akutagawa, K. Nabeya, *K. Kinbara, Chem. Asian J., 14, 141–148 (2018), DOI: 10.1002/asia.201801372

総説・解説
"【座談会】はたらく分子マシン, ナノ世界のエネルギー変換へ”
金原 数, 現代科学2022年3月号 , 現代科学,, 612,46-50 (2022)

タンパク質を模倣した人工発動分子の創製に向けて -膜タンパク質を模倣した合成化学的アプローチ-
金原 数, 化学と工業 , 73,457-459 (2020)

Session 2SDA—Nonequilibrium energetics of biological molecular machines
*S. Toyabe, C. B. Li, K. Kinbara, Biophys Rev. , 12, 273-274 (2020), DOI: 10.1007/s12551-020-00634-3

Introduction: Molecular Motors
*R. Iino, *K. Kinbara, *Z. Bryant, Chem. Rev., 120, 1-4 (2020), DOI: 10.1021/acs.chemrev.9b00819

Biomimetic and technomimetic single molecular machines
C. Kammerer ,G. Erbland ,Y. Gisbert ,T. Nishino ,K. Yasuhara , *G. Rapenne, Chem. Lett. , 48, 299-308 (2019), DOI:10.1246/cl.181019

書籍
・「Building and Probing Small, in Advances in Atom and Single Molecule Machines」, C. Joachim (Ed),
“Prototypes of molecular gears with an organometallic piano-stool architecture”, S. Abid, G. Erbland, C. Kammerer, *G. Rapenne, Springer , (2020), ISBN: 978-3-030-56776-7

・「Building and Probing Small, in Advances in Atom and Single Molecule Machines」, C. Joachim (Ed),
“Design and synthesis of a nano-winch”, Y. Gisbert, A.M. Sirven, G. Rapenne, *C. Kammerer, Springer , (2020), ISBN: 978-3-030-56776-7

・「タンパク質工学ハンドブック」, 津本浩平・浜窪隆雄 (Eds), “膜タンパク質を模倣した人工分子の創成”
金原 数, 第4編第7章, NTS出版 (2020), ISBN: 978-4-86043-537-0

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